Angelina Jolie and Brad Pitt
This one was a major shocker. Just as surprising as the A-list duo of Brad Pitt and Angelina Jolie burst onto the scene, it ended as well. Their romance started on the set of “Mr. & Mrs. Smith” in 2005 when Pitt was married to Jennifer Aniston. The long-time couple got engaged in 2012 and, at the insistence of their six children, married at their French chateau in 2014. But the relationship devolved during Jolie’s 2015 “By the Sea” directorial effort in which the couple co-starred.
By the end of 2016, there were accusations of abuse and then a divorce. The decision to divorce has been taken “for the family’s health,” they stated. Brad and Angelina may have separated back in 2016, but it was not until 2019 that a judge legally ended their union. The move did not seem to be linked to any new relationships and, in addition, after the decision was made, neither Angelina nor Brad have moved on with a public relationship, while rumors about Pitt’s love life are always circulating.