The Most Surprising Separations of Famous Couples - Page 3 of 8

Jesse James and Sandra Bullock

In 2005, after meeting Sandra Bullock while she was visiting the set of his Discovery Channel program, Monster Garage, Jesse James married Bullock. Coming off her glorious Oscar achievement, she discovered that her husband of five years had cheated on her with not one but multiple women. During the controversy, she remained commendably quiet and filed for a divorce that was settled in just 60 days.